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C14H12O2
Области применения:
1. Вспомогательная текстильная промышленность: используется в качестве направляющего агента при крашении, выравнивающего агента, ремонтного агента и т. д.
2. Ароматизаторы и парфюмерная промышленность: единственный растворитель для мускуса, фиксатор.
3. Фармацевтическая промышленность: например, лечение чесотки.
4. Пластификатор.
Имена и идентификаторы
| Имя | Бензилбензоат |
| Синонимы | Аскабин Бенилат Ascabiol Scabagen Vanzoate VANZOATE(R) Бензиловый эфир VENZONATE(R) Бензилбензоат Benzyl benzoate BP BENZOATO DE BENCILO Benzyl phenylformate Phenylmethyl benzoate Бензиловый эфир бензойной кислоты Benzyl benzene carboxylate Benzyl alcohol benzoic ester Benzoic acid phenylmethyl ester |
| CAS | 120-51-4 |
| EINECS | 204-402-9 |
| InChI | InChI=1/C14H12O2/c15-14(13-9-5-2-6-10-13)16-11-12-7-3-1-4-8-12/h1-10H,11H2 |
| InChIKey | SESFRYSPDFLNCH-UHFFFAOYSA-N |
Физико-химические свойства
| Молекулярная формула | C14H12O2 |
| Молярная масса | 212.24 |
| Плотность | 1.118 г / мл при 20 ° C (лит.) |
| Температура плавления | 17-20 °С (лит.) |
| Болинг Точка | 323-324 °С (лит.) |
| Точка возгорания | 298 ° F |
| Номер JECFA | 24 |
| Растворимость воды | Практически нерастворимый |
| Растворимость | Miscible with ethanol, alcohol, chloroform, ether, oils |
| Давление пара | 1 мм рт.ст. (125 ° C) |
| Внешний вид | Прозрачная жидкость |
| Цвет | Бесцветный прозрачный |
| Merck | 14,1127 |
| BRN | 2049280 |
| Условия хранения | 2-8 ° C |
| Стабильность | Стабильная. Вещества, которых следует избегать, включают сильные окислители. Горюче. |
| чувствительный | Чувствителен к свету |
| Показатель преломления | n20 / D 1.568 (освещен). |
| MDL | MFCD00003075 |
| Физические и химические свойства | Character white oily liquid, slightly viscous, pure product is flake crystal. There is a weak plum, almond aroma. температура плавления 21 ℃ температура кипения 323~324 ℃ относительная плотность 1.1121 показатель преломления 1.5690 температура вспышки 148 ℃ solubility-insoluble in water and glycerol, soluble in most organic solvents. |
| Используйте | It is used for fixative of solvent and essence of Musk, substitute of camphor, also used for preparation of pertussis medicine, asthma medicine, etc |
Риск и безопасность
| Коды рисков | R22 – Вредно при проглатывании. R51/53 – Токсично для водных организмов, может вызывать долгосрочные неблагоприятные последствия в водной среде. |
| Описание безопасности | S25 – Избегать попадания в глаза. S61 – Избегать попадания в окружающую среду. См. специальные инструкции/паспорта безопасности. S46 — При проглатывании немедленно обратитесь к врачу и покажите этот контейнер или этикетку. |
| Идентификаторы ООН | UN 3082 9 / PGIII |
| WGK Германия | 2 |
| RTECS | DG4200000 |
| ЗКТВ | Да |
| Код ТН ВЭД | 29163100 |
| Класс опасности | 9 |
| Токсичность | LD50 in rats, mice, rabbits, guinea pigs (g/kg): 1.7, 1.4, 1.8, 1.0 orally (Draize) |
Справочная информация
| FEMA | 2138 | БЕНЗИЛБЕНЗОАТ |
| LogP | 4 при 20 ℃ |
| Точка замерзания | the freezing point of benzyl benzoate is ≥ 17 ℃. in winter, because it condenses into a solid, when using, the benzyl benzoate package can be placed in a drying room (temperature 35-70 ℃) or warm water (temperature 40-90 ℃) water bath for use after melting. |
| Анализ содержания | determined by method 1 in ester content determination method (OT-18). The amount of sample taken is 1g. Equivalent factor in calculation (e) |
| токсичность | ADI 0~5 mg/kg(FAO/WHO,1994). LD50500mg/kg (rat, oral). |
| лимит использования | FEMA(mg/kg): soft drink 4.5; Cold drink 12; Candy 39; Baked food 33; Gum sugar 280. Moderate limit (FDA § 172.515,2000). |
| использование | is a good fixer, diluent or solvent in essence, especially in flower fragrance. It can be used as a modifier in heavy floral and oriental fragrance types, tuberose, ylang ylang, lilac, gardenia and other fragrance types. It is also a stabilizer for high-carbon aldehyde or alcohol fragrances, and a good solvent for certain solid fragrances. It is also commonly used as a fixer in the formulation of edible flavors. benzyl benzoate can be used as a solvent for cellulose acetate, perfume fixing agent, candy flavoring agent, plastic plasticizer and insect repellent. When the product is used as a spice, the product specification can refer to Shanghai Q/QBH68-79, and the ester content is above 99%. It can be used as a fixer for a variety of floral flavors, and is also the only best solvent for solid flavors that are difficult to dissolve in flavors. It can dissolve artificial musk in flavors (1kg benzyl benzoate can dissolve 0.45kg sunflower musk, 0.205kg ketone musk or 0.28kg xylene musk), and is also used to prepare whooping cough medicine, asthma medicine, etc. In addition, benzyl benzoate is also used in textile auxiliaries, scabies creams, pesticide intermediates, etc.; in textile auxiliaries, mainly used as a dye guide, leveling agent, repair agent, etc.; in polyester and compact fiber The field is widely used. |
| Способ производства | Heat reaction of sodium benzyl alcohol with benzaldehyde, or reaction of sodium benzoate with benzyl chloride. Ethyl benzoate and benzyl alcohol are also used in the perfume industry. It is formed by the co-thermal esterification of sodium benzoate and benzoyl chloride in the presence of triethylamine. Under the conditions of stirring and cooling, sodium is dissolved in benzyl alcohol, then benzaldehyde is slowly added, and the effect is completely heated in a water bath for 1~2h, the precipitated oil layer is separated, washed and fractionated. Benzyl alcohol is esterified with benzoic acid. It is obtained by transesterification and fractionation of benzoate with benzyl alcohol using sodium carbonate as a catalyst. Br> benzyl benzoate naturally exists in Peruvian balsam, tuberose, carnation and tulu balsam, etc. It is usually produced by chemical synthesis in industry. 7g(0.07 mo1) benzyl alcohol was added to a 100mL round bottom flask, 0.3g(0.013mol) of sodium metal was added to dissolve in it within 30min, and after cooling to room temperature, it was slowly added into a 250mL three-mouth bottle containing 45.4g(0.43 mo1) benzaldehyde. The mixture heats up due to the reaction and is cooled with water so that the temperature does not exceed 50~60 ℃. After about 30min, when the temperature stopped rising, heating in the water bath to continue the reaction for 1h. After the reactants are cooled, use 40mI. Wash with water twice. The obtained oil is distilled under reduced pressure. Benzyl alcohol, unreacted benzaldehyde and a small amount of water are first distilled, and then a fraction of 184~185 ℃(2kPa) is collected to obtain about 40g of product. 2C6H5CHO→ C6H5COOCH2C6H5 benzyl alcohol and ethyl benzoate are transesterified in the presence of sodium carbonate. After the reaction is over, the ethanol is removed by atmospheric distillation, and then the benzyl alcohol is removed by vacuum distillation. After cooling, the product is washed, layered, dried, and finally distilled under reduced pressure. C6H5COOCH2CH3 C6H5CH2OH[Na2CO3]→C6H5COOCH2C6H5 CH3CH2OH |
| Каталог | пестицид |
| классификация токсичности | отравление |
| Острая токсичность | oral-rat LD50:1700 mg/kg; Oral-mouse LD50: 1400 mg/kg |
| Explosive hazard characteristics | Intense reaction with oxidant |
| характеристики опасности воспламеняемости | more flammable liquid; combustion produces stimulating smoke |
| Характеристики хранения и транспортировки | ventilation and low temperature drying; storage with oxidant |
| огнетушащее средство | dry powder, carbon dioxide, mist water |
| температура самовоспламенения | 896 ° F |
Фабрика и отгрузка
