Аминотри(метиленфосфоновая кислота)

Краткое описание:

Номер CAS 6419-19-8Содержание 50%Упаковка 250кг / барабанИмена и идентификаторыИмяНитрилотрим...

Подробное описание

Номер CAS 6419-19-8

Содержание 50%

Упаковка 250кг / барабан

Имена и идентификаторы

ИмяНитрилотриметилентрифосфоновая кислота
СинонимыАТМП
АТМПА
Деквест 2000
БРИКЕСТ 301-50А
ТРИС(ФОСФОНОМЕТИЛ)АМИН
НИТРИЛОТРИМЕТАНФОСФОНОВАЯ КИСЛОТА
Аминотриметиленфосфоновая кислота
Нитрилотри(метилфосфоновая кислота)
НИТРИЛОТРИ(МЕТИЛФОСФОНОВАЯ КИСЛОТА)
Аминотриметиленфосфоновая кислота
Аминотри(метиленфосфоновая кислота)
НИТРИЛОТРИС (МЕТИЛЕНФОСФОНОВАЯ КИСЛОТА)
Трис (метиленфосфоновая кислота) амин
АМИНО,ТРИС(МЕТИЛЕНФОСФОНОВАЯ КИСЛОТА)
Амино трис (метиленфосфоновая кислота)
Нитрилотриметилентрифосфоновая кислота
(аммониотриметандиил)трис(фосфонат)
нитрилотриметилентрис(фосфоновая кислота)
НИТРИЛОТРИС(МЕТИЛЕН)ТРИФОСФОНОВАЯ КИСЛОТА
Аминотриметиленфосфоновая кислота (АТМФ)
трицинк (нитрилотриметандиил)трис(фосфонат)
тринатрий ({[(гидроксифосфинато)метил](фосфонометил)амино}метил)фосфонат
триаммоний ({[(гидроксифосфинато)метил](фосфонометил)амино}метил)фосфонат
CAS6419-19-8
EINECS229-146-5
InChIInChI=1/C3H12NO9P3/c5-14(6,7)1-4(2-15(8,9)10)3-16(11,12)13/h1-3H2,(H2,5,6,7)(H2,8,9,10)(H2,11,12,13)/p-5
InChIKeyYDONNITUKPKTIG-UHFFFAOYSA-N

6419-19-8 – Физико-химические свойства

Молекулярная формулаC3H12NO9P3
Молярная масса299.05
Плотность1.3 г/м при 25°C
Температура плавления~215°C (dec.)
Болинг Точка746.2 ± 70.0 ° C (прогноз)
Точка возгорания405.1 ° C
Растворимость воды500 г/л при 20 ℃
РастворимостьWater (Slightly, Heated)
Давление пара0 Па при 25 ℃
Внешний видSOLID
ЦветБелый
BRN1715724
рКа0.56 ± 0.10 (прогнозируемый)
PH0.46
Условия храненияЗапечатанный в сухом, комнатной температуре
СтабильностьСтабильная. Несовместим с основаниями, сильными окислителями.
MDLMFCD00002138
Физические и химические свойстваMiscible with water. At 200 ℃, it has excellent scale inhibition performance, good stability and excellent effect on calcium carbonate scale. It can form stable complexes with iron, copper, aluminum, zinc and other metal ions, and has good dispersion performance. When the dosage is more than 40ppm, it also has good corrosion inhibition performance.
ИспользуйтеCooling water system, oil pipeline and boiler scale, it can be used as high hardness, high salinity and other poor water quality of the oil pipeline scale inhibitor.

6419-19-8 – Риск и безопасность

Коды рисковR36 – Раздражает глаза.
R34 — Вызывает ожоги.
R35 – Вызывает серьезные ожоги
Описание безопасностиS26 – При попадании в глаза немедленно промыть большим количеством воды и обратиться к врачу.
S45 – В случае несчастного случая или плохого самочувствия немедленно обратитесь к врачу (по возможности покажите этикетку).
S36/37/39 – Носите подходящую защитную одежду, перчатки и средства защиты глаз/лица.
S25 – Избегать попадания в глаза.
S44 -
S36 – Носите подходящую защитную одежду.
Идентификаторы ООН3265
WGK Германия1
RTECSSZ9860000
F-КОДЫ МАРКИ FLUKA3-9
Код ТН ВЭД29319090
Класс опасности8
Группа упаковкиIII

Справочная информация

LogP-3.5
Введениеchloro-trimethylene phosphonic acid, also known as amino-trimethylene phosphonic acid (ATMP), has good chelation, low limit inhibition and lattice distortion effect. Scale formation, particularly calcium carbonate scale formation, can be prevented by scaling salts in water. Amino trimethylene phosphonic acid is chemically stable in water and is not easily hydrolyzed. When the concentration is high in water, it has good corrosion inhibition effect.
Процесс подачи заявкиchloro-trimethylene phosphonic acid is used in the recirculating cooling water system of thermal power plant, refinery and oil field reinjection water system. Can play a role in reducing metal equipment or pipeline corrosion and scaling. Amino trimethylene phosphonic acid is used as a metal ion chelating agent in textile printing and dyeing and other industries, and can also be used as a metal surface treatment agent.
подготовка(1) 15g of yellow phosphorus is introduced into a closed reactor for nitrogen deaeration;(2) after heating to 45 ℃, a small amount of high purity oxygen is introduced into the reaction kettle, which is not completely burned under insufficient oxygen, and phosphorus trioxide (P2O3) is obtained in the closed reaction kettle;(3) add 90g of water and 40g of ammonium chloride to the closed reaction kettle, stir and mix for 60min at 20 ℃, add 100g of formaldehyde solution with mass fraction of 37% Dropwise after stirring, and then heat to 50 ℃, reaction 2H, then 1.5 ℃/min to 110 ℃, reaction 1H;(4) after the reaction is complete, control the temperature of 125 ℃ for distillation, chloro-trimethylene phosphonic acid can be obtained when no material is distilled out.
ИспользуйтеATMP is chemically stable in water and is not susceptible to hydrolysis. When the concentration of amino trimethylene phosphonic acid in water is high, it has a good corrosion inhibition effect. ATMP is used for recirculating cooling water in thermal power plants, oil refineries and oil field reinjection systems. Amino trimethylene phosphonic acid can act to reduce corrosion and scaling of metal equipment or pipelines. ATM is used as a metal ion chelating agent in textile printing and dyeing and other industries, and can also be used as a metal surface treatment agent. Solid crystalline powder, soluble in water, easy to absorb moisture, easy to transport and use, especially suitable for winter cold area. Due to the high purity of ATMP, it can be used as metal chelating agent and metal surface treatment agent in textile printing and dyeing industry.
ATMP has good integration, low limit inhibition and lattice distortion. Scale formation, particularly calcium carbonate scale formation, can be prevented by scaling salts in water. ATMP is chemically stable in water and is not easily hydrolyzed. When the concentration in water is high, ATMP has good corrosion inhibition effect. It is used in circulating cooling water of thermal power plant, refinery and oil field reinjection system. Can play a role in reducing metal equipment or pipeline corrosion and scaling. ATMP is used as a metal ion chelating agent in textile printing and dyeing and other industries, and can also be used as a metal surface treatment agent. ATMP solid is crystalline powder, soluble in water, easy to absorb moisture, easy to transport and use, especially suitable for winter cold area. Due to its high purity, it can be used as metal chelating agent and metal surface treatment agent in textile printing and dyeing industry.
The Scale Inhibitor of cooling water system, oil pipeline and boiler can be used as Scale Inhibitor of oil pipeline with high hardness, high salinity and other poor water quality.
scale and corrosion inhibitors for cooling water, boiler water and oilfield water treatment
circulating cooling for thermal power plants and refineries
Water treatment agentamino trimethylene phosphonic acid (aminotrimethylene phosphonic acid) solid is crystalline powder, soluble in water, easy to absorb moisture, it has good chelation, low limit inhibition and lattice distortion. It has excellent scale inhibition effect below 200 ℃, low toxicity, good thermal stability, can dissociate into six positive and negative ions in water, and can be applied to iron, copper, aluminum, zinc, calcium, magnesium and other metal ions chelate to form a stable complex, especially for carbonate scale. And with polyphosphate, polycarboxylate, nitrite has good synergistic ability. There is a good corrosion inhibition in 40mg/L.
aminotrimethylenephosphonic acid (ATMP) is a methylene phosphonic acid type compound, which is one of the agents used earlier in water treatment agents. Because it can form double five-membered ring chelate with Ca2 ,Mg2 ,Zn2 ,Fe2 and other metal ions in water, it has good effect of inhibiting calcium carbonate scale and corrosion inhibition performance on carbon steel. ATMP is an organic phosphorus acid scale inhibitor, which is not easy to hydrolyze and has a temperature resistance of more than 100°C. Dosage is relatively low, has better anti-scaling effect.
способ использованияamino trimethylene phosphonic acid ATM is often combined with other organic phosphoric acid, polycarboxylic acid or salt into organic alkaline water treatment agent, for a variety of different water quality under the circulating cooling water system. The dosage of 1~20mg/L is better, when used as corrosion inhibitor, the dosage is 20~60mg/L. Amino trimethylene phosphonic acid is stored in a cool and ventilated place indoors, moisture-proof and protected from sun exposure.
amino trimethylene phosphonic acid is often combined with other organic phosphonic acids, polycarboxylic acids or salts to form organic water treatment agents, which are used in circulating cooling water systems under different water quality conditions. The dosage of 1~20mg/L is better; When used as corrosion inhibitor, the dosage is 20~60mg/L. Amino trimethylene phosphonic acid is acidic, attention should be paid to labor protection during operation, should avoid contact with skin, eyes and so on, and should be washed with plenty of water immediately after contact.
amino trimethylene phosphonic acid (aminotrimethylene phosphonic acid) applicationsused in thermal power plants, refineries, petrochemical, circulating cooling water of chemical fertilizer plant and oilfield reinjection water system. It is especially suitable for systems with high calcium hardness and low concentration ratio, such as power plants. And large hardness, high salinity, poor water quality conditions of the oil pipeline Scale Inhibitor, can play a role in reducing corrosion and scaling of metal equipment and pipelines. It is used as a metal ion chelating agent and a metal surface treatment agent in textile printing and dyeing and other industries.
reference quality standardproject indicators in accordance with HG/T 2841-1997 in accordance with HG/T2841-2005 appearance colorless or light yellow transparent liquid white crystalline powder active ingredient (in ATMP)% ≥ 50.0 50.0 95.0 amino trimethylenephosphonic acid content% ≥ — 40.0 88.0 phosphorous acid (as PO33-)% ≤ 5.0 3.5 — phosphoric acid (as PO43-)% ≤ 1.0 0.8 0.8 chloride (as Cl-)% ≤ 3.5 2.0 1.0 iron (as Fe2 +) content mg/L ≤ -20.0 20.0 density (20 ℃)g/cm3 ≥ 1.28 1.30-pH(1% aqueous solution) 1.5-2.5-1.5-2.5 2.0

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